Formation of Monomeric Terminal Chalcogenides by Template‐Induced Disilylchalcogenide Elimination; the Crystal Structures of [ETa{(Me 3 SiNCH 2 CH 2 ) 3 N}] (E  Se, Te) | Zendy

Christou Victor | Zendy; Arnold John | Zendy

Premium

Formation of Monomeric Terminal Chalcogenides by Template‐Induced Disilylchalcogenide Elimination; the Crystal Structures of [ETa{(Me 3 SiNCH 2 CH 2 ) 3 N}] (E  Se, Te)

Author(s) -

Christou Victor,

Arnold John

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199314501

Subject(s) - tantalum , yield (engineering) , monomer , crystallography , terminal (telecommunication) , telluride , ligand (biochemistry) , chemistry , center (category theory) , crystal structure , stereochemistry , materials science , computer science , polymer , organic chemistry , telecommunications , metallurgy , biochemistry , receptor

Ever more useful is the triamido ligand [(Me 3 Si)NCH 2 CH 2 ]3N 3− , which now has shown its worth in stabilizing a terminal selenido and telluride unit at a tantalum center. Treatment of the dichloride 1 with (thf) 2 LiESi(SiMe 3 ) 3 , E Se or Te, affords the stable complexes 2 and 3 in good yield. The products can be characterized by spectroscopy and X‐ray crystallography.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research