The Dimeric Tris(lithioarsino)germane  t BuGe[As(Si i Pr 3 )Li] 3 : A Self Assembled, Solvent Free Lithium–Main Group Element Aggregate with a Ge 2 As 6 Li 6  Rhombododecahedral Frame work | Zendy

Zsolnai Laszlo | Zendy; Huttner Gottfried | Zendy; Driess Matthias | Zendy

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The Dimeric Tris(lithioarsino)germane t BuGe[As(Si i Pr 3 )Li] 3 : A Self Assembled, Solvent Free Lithium–Main Group Element Aggregate with a Ge 2 As 6 Li 6 Rhombododecahedral Frame work

Author(s) -

Zsolnai Laszlo,

Huttner Gottfried,

Driess Matthias

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199314391

Subject(s) - lithium (medication) , germane , group (periodic table) , chemistry , solvent , main group element , aggregate (composite) , crystallography , element (criminal law) , medicinal chemistry , germanium , materials science , silicon , organic chemistry , nanotechnology , catalysis , medicine , transition metal , endocrinology , political science , law

Without problems and from “within” , that is, by Li–As multicenter bonds and LiHC interactions, is the description of how the electronic stabilization of the Li atoms appears to function in the Ge 2 As 6 Li 6 framework of 1 , which is shielded by bulky t Bu and Si i Pr 3 substituents. The lithium‐rich main group element aggregate 1 is formed in the reaction of t BuGeF 3 with LiAs(Si i Pr 3 )H in the presence of t BuLi. • As, Ge, ◯Li, ⊗ R 1 Si i Pr 3 , ⊙ R 2 t Bu.

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