Hydrolysis to a Complex with a Central, Octahedral (μ 6 ‐O)In 6  Unit | Zendy

Hegetschweiler Kaspar | Zendy; Ghisletta Michele | Zendy; Fässler Thomas F. | Zendy; Nesper Reinhard | Zendy

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Hydrolysis to a Complex with a Central, Octahedral (μ 6 ‐O)In 6 Unit

Author(s) -

Hegetschweiler Kaspar,

Ghisletta Michele,

Fässler Thomas F.,

Nesper Reinhard

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199314261

Subject(s) - octahedron , hydrolysis , unit (ring theory) , crystallography , center (category theory) , group (periodic table) , chemistry , element (criminal law) , symmetry (geometry) , stereochemistry , mathematics , crystal structure , geometry , organic chemistry , mathematics education , political science , law

Hitherto unknown for main group elements was the structural element M 6 O 13 , which has now been found in the cation 1 , taci = 1,3,5‐triamino‐1,3,5‐trideoxyinositol. In the In 6 O 13 core with a μ 6 ‐oxo center and approximate O h symmetry, the OIn 6 unit is completely shielded by the six‐coordinate (taci–3 H) ligands, which explains the surprising stability of 1 toward further hydrolysis.

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