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Hydrolysis to a Complex with a Central, Octahedral (μ 6 ‐O)In 6 Unit
Author(s) -
Hegetschweiler Kaspar,
Ghisletta Michele,
Fässler Thomas F.,
Nesper Reinhard
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199314261
Subject(s) - octahedron , hydrolysis , unit (ring theory) , crystallography , center (category theory) , group (periodic table) , chemistry , element (criminal law) , symmetry (geometry) , stereochemistry , mathematics , crystal structure , geometry , organic chemistry , mathematics education , political science , law
Hitherto unknown for main group elements was the structural element M 6 O 13 , which has now been found in the cation 1 , taci = 1,3,5‐triamino‐1,3,5‐trideoxyinositol. In the In 6 O 13 core with a μ 6 ‐oxo center and approximate O h symmetry, the OIn 6 unit is completely shielded by the six‐coordinate (taci–3 H) ligands, which explains the surprising stability of 1 toward further hydrolysis.