Sterically Controlled, Metal‐Induced Synthesis of a 1‐Thia‐2, 4‐diphosphole | Zendy

Lindner Ekkehard | Zendy; Haase Cornelius | Zendy; Mayer Hermann A. | Zendy; Kemmler Martin | Zendy; Fawzi Riad | Zendy; Steimann Manfred | Zendy

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Sterically Controlled, Metal‐Induced Synthesis of a 1‐Thia‐2, 4‐diphosphole

Author(s) -

Lindner Ekkehard,

Haase Cornelius,

Mayer Hermann A.,

Kemmler Martin,

Fawzi Riad,

Steimann Manfred

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199314241

Subject(s) - steric effects , chemistry , cleavage (geology) , cycloaddition , metal , molecule , medicinal chemistry , stereochemistry , bond cleavage , crystallography , materials science , catalysis , organic chemistry , fracture (geology) , composite material

Cleavage of the PS bond of an R 2 PS function (R cyclohexyl), bound in a η 2 fashion to Mn(CO) 4 , through insertion of R 1 CP, followed by subsequent [2+2] cycloaddition of the product and a second molecule of R 1 CP, leads to the thiadiphosphole 1 . By decreasing the size of R stepwise (→ Ph → Me), the bicycle 2 and the pentacycle 3 can be formed. [Mn] Mn(CO) 3 , R1 t Bu.

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