Zirconium Phosphite (3,3′,5,5′‐Tetramethylbiphenyl)diphosphonate, a Microporous, Layered, Inorganic–Organic Polymer | Zendy

Alberti Giulio | Zendy; Costantino Umberto | Zendy; Marmottini Fabio | Zendy; Vivani Riccardo | Zendy; Zappelli Piergiorgio | Zendy

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Zirconium Phosphite (3,3′,5,5′‐Tetramethylbiphenyl)diphosphonate, a Microporous, Layered, Inorganic–Organic Polymer

Author(s) -

Alberti Giulio,

Costantino Umberto,

Marmottini Fabio,

Vivani Riccardo,

Zappelli Piergiorgio

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199313571

Subject(s) - microporous material , zirconium , molecular sieve , polymer , catalysis , biphenyl , organic polymer , zirconium phosphate , materials science , chemical engineering , chemistry , polymer chemistry , inorganic chemistry , phosphate , organic chemistry , engineering

Pores of uniform size are found in the title compound (a structural model is shown on the right), in which parallel layers of a zirconium phosphate are joined by biphenyl “pillars”. The structure of this polymer, which may have potential as a shape‐selective catalyst or a molecular sieve, is reminiscent of the architecture of a Greek temple.

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