Structure and Electrochemical Behavior of the Paramagnetic Anion [Ir 14 (CO) 27 ] − , Possessing a Trigonal Bipyramidal Arrangement of Metal Atoms | Zendy

Pergola Roberto Delta | Zendy; Garlaschelli Luigi | Zendy; Manassero Mario | Zendy; Masciocchi Norberto | Zendy; Zanello Piero | Zendy

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Structure and Electrochemical Behavior of the Paramagnetic Anion [Ir 14 (CO) 27 ] − , Possessing a Trigonal Bipyramidal Arrangement of Metal Atoms

Author(s) -

Pergola Roberto Delta,

Garlaschelli Luigi,

Manassero Mario,

Masciocchi Norberto,

Zanello Piero

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199313471

Subject(s) - trigonal bipyramidal molecular geometry , crystallography , cluster (spacecraft) , chemistry , ion , electrochemistry , bipyramid , pentagonal bipyramidal molecular geometry , metal , paramagnetism , trigonal pyramidal molecular geometry , atom (system on chip) , trigonal crystal system , center (category theory) , inorganic chemistry , crystal structure , physics , electrode , organic chemistry , computer science , programming language , embedded system , quantum mechanics

The structure hardly changes when the cluster [Ir 14 (CO) 27 ] − ( 1 ) is reduced to the dianion or oxidized to the neutral compound. The 14 Jr atoms form a trigonal bipyramid, which contains an Jr atom at the center of every edge (see picture). The terminal CO ligands cover the metal framework completely.

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