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Carbenes in Constrained Systems I: 1,3 CH, Insertion Reaction of Adamantylidene within the β‐Cyclodextrin Cavity
Author(s) -
Brinker Udo H.,
Buchkremer Rüdiger,
Kolodziejczyk Margaret,
Kupfer René,
Rosenberg Murray,
Poliks Mark D.,
Orlando Mario,
Gross Michael L.
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199313441
Subject(s) - cyclodextrin , carbene , intermolecular force , chemistry , inclusion (mineral) , mass spectrum , photodissociation , stereochemistry , crystallography , catalysis , photochemistry , molecule , mass spectrometry , organic chemistry , mineralogy , chromatography
The first intra‐ and intermolecular carbene insertions within any constrained molecular reaction vessel was detected in the photolysis of the solid inclusion complex 1 ·β‐cyclodextrin(CD). NMR and/or FAB mass spectra reveal the formation of products such as 2 ·β‐CD and 3 ·β‐CD.