Carbenes in Constrained Systems I: 1,3 CH, Insertion Reaction of Adamantylidene within the β‐Cyclodextrin Cavity | Zendy

Brinker Udo H. | Zendy; Buchkremer Rüdiger | Zendy; Kolodziejczyk Margaret | Zendy; Kupfer René | Zendy; Rosenberg Murray | Zendy; Poliks Mark D. | Zendy; Orlando Mario | Zendy; Gross Michael L. | Zendy

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Carbenes in Constrained Systems I: 1,3 CH, Insertion Reaction of Adamantylidene within the β‐Cyclodextrin Cavity

Author(s) -

Brinker Udo H.,

Buchkremer Rüdiger,

Kolodziejczyk Margaret,

Kupfer René,

Rosenberg Murray,

Poliks Mark D.,

Orlando Mario,

Gross Michael L.

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199313441

Subject(s) - cyclodextrin , carbene , intermolecular force , chemistry , inclusion (mineral) , mass spectrum , photodissociation , stereochemistry , crystallography , catalysis , photochemistry , molecule , mass spectrometry , organic chemistry , mineralogy , chromatography

The first intra‐ and intermolecular carbene insertions within any constrained molecular reaction vessel was detected in the photolysis of the solid inclusion complex 1 ·β‐cyclodextrin(CD). NMR and/or FAB mass spectra reveal the formation of products such as 2 ·β‐CD and 3 ·β‐CD.

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