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Dicyanopolyynes: Formation of New Rod‐Shaped Molecules in a Carbon Plasma
Author(s) -
Grösser Thomas,
Hirsch Andreas
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199313401
Subject(s) - graphite , carbon fibers , rod , molecule , plasma , evaporation , helium , chemistry , materials science , chemical engineering , crystallography , organic chemistry , thermodynamics , composite number , nuclear physics , physics , composite material , medicine , alternative medicine , pathology , engineering
Molecular rods such as 1 with a row of up to 18 atoms were obtained in preparative amounts by evaporation of graphite in the presence of helium and dicyanogen. The same experiments with chlorine as the reaction partner for the C plasma led to perchlorinated aromatic compounds. The carbon frameworks of these compounds are sections of the C 60 structure.