Premium
Giant Organometallic Networks Derived from Ferrocenepolysulfides
Author(s) -
Galloway Collin P.,
Rauchfuss Thomas B.
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199313191
Subject(s) - ferrocene , alkyl , gel permeation chromatography , derivative (finance) , chemistry , polymerization , polymer , polymer chemistry , flue gas desulfurization , metallocene , permeation , organometallic chemistry , organic chemistry , catalysis , biochemistry , electrode , membrane , financial economics , economics , electrochemistry
Desulfurization with tributylphosphane converts the ferrocenepolysulfide 1 into three‐dimensional network polymers. These consist of ferrocene subunits interconnected by oligosulfide crosslinks. Gel permeation chromatography on an analogous polymerized alkyl derivative of 1 indicates molecular weights in excess of 10 6 Da. •=Fe.