Giant Organometallic Networks Derived from Ferrocenepolysulfides | Zendy

Galloway Collin P. | Zendy; Rauchfuss Thomas B. | Zendy

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Giant Organometallic Networks Derived from Ferrocenepolysulfides

Author(s) -

Galloway Collin P.,

Rauchfuss Thomas B.

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199313191

Subject(s) - ferrocene , alkyl , gel permeation chromatography , derivative (finance) , chemistry , polymerization , polymer , polymer chemistry , flue gas desulfurization , metallocene , permeation , organometallic chemistry , organic chemistry , catalysis , biochemistry , electrode , membrane , financial economics , economics , electrochemistry

Desulfurization with tributylphosphane converts the ferrocenepolysulfide 1 into three‐dimensional network polymers. These consist of ferrocene subunits interconnected by oligosulfide crosslinks. Gel permeation chromatography on an analogous polymerized alkyl derivative of 1 indicates molecular weights in excess of 10 6 Da. •=Fe.

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