Complexation of Methane and Chlorofluorocarbons by Cryptophane‐A in Organic Solution | Zendy

Garel Laurent | Zendy; Dutasta JeanPierre | Zendy; Collet André | Zendy

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Complexation of Methane and Chlorofluorocarbons by Cryptophane‐A in Organic Solution

Author(s) -

Garel Laurent,

Dutasta JeanPierre,

Collet André

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199311691

Subject(s) - methane , supercritical fluid , molecule , host (biology) , organic molecules , chemistry , chemical physics , materials science , photochemistry , organic chemistry , ecology , biology

Equivalent to a supercritical fluid is a description of the state of the methane molecule in the interior of the host cavity of a cryptophane molecule. The CH 4 –cryptophane complex (shown on the right) is amazingly stable even at room temperature ( K a = 130 M −1 ), and its half‐life is 6 μs. The findings of this study shed light on the bonding between neutral guest and neutral host molecules.

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