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Golcondane: A Novel, Caged, Nonacyclic C 20 H 24 ‐Hydrocarbon of D 2d Symmetry
Author(s) -
Mehta Goverdhan,
Reddy S. Hari Krishna
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199311601
Subject(s) - cyclopentadiene , cycloaddition , intramolecular force , symmetry (geometry) , hydrocarbon , product (mathematics) , chemistry , stereochemistry , crystallography , physics , mathematics , organic chemistry , catalysis , geometry
In only five steps the title compound 1 can be synthesized from a bisnorbornenobenzoquinone. Intermediates en route to 1 may provide access to other interesting polycycles, for example to cyclic 1,4‐tetramers of 1,3‐cyclopentadiene such as 3 . Golcondane 1 can be considered as a dieter of 2 or a product of a double intramolecular [2 + 2] cycloaddition of 3 .
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