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Ylide‐Substituted Thioxophosphanes and Dithioxophosphoranes
Author(s) -
Jochem Georg,
Nöth Heinrich,
Schmidpeter Alfred
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199310891
Subject(s) - ylide , halogen , monomer , chalcogenide , chemistry , alkyl , crystallography , phosphorus , polymer chemistry , stereochemistry , organic chemistry , polymer
A monomeric phosphorus(III)chalcogenide , thioxophosphane 1 was isolated and structurally characterized for the first time. Hitherto, thioxophosphanes of the type RPS, (R = halogen, alkyl, etc.) could be characterized only indirectly, because they are so reactive. The polar resonance structure is important for the description of the bonding of 1 .