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Organometallic Molecular Trees as Multielectron and Multiproton Reservoirs: CpFe + ‐Induced Nonaallylation of Mesitylene and Phase‐Transfer Catalyzed Synthesis of a Redox‐Active Nonairon Complex
Author(s) -
Moulines Françoise,
Djakovitch Laurent,
Gloaguen Bruno,
Thiel Werner,
Fillaut JeanLuc,
Delville MarieHélène,
Astruc Didier,
Boese Roland
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199310751
Subject(s) - mesitylene , redox , catalysis , chemistry , phase (matter) , photochemistry , electron transfer , inorganic chemistry , organic chemistry
A reservoir of 9 electrons and 27 protons , complex 1 has 8±1 quasi‐equivalent redox centers. It is prepared from [CpFe(η 6 ‐mesitylene)] + by nonaallylation of the three methyl substituents, demetalation, conversion into the corresponding nonaol, and phasetransfer‐catalyzed reaction with [CpFe(FC 6 H 4 Me)].

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