Organometallic Molecular Trees as Multielectron and Multiproton Reservoirs: CpFe + ‐Induced Nonaallylation of Mesitylene and Phase‐Transfer Catalyzed Synthesis of a Redox‐Active Nonairon Complex | Zendy

Moulines Françoise | Zendy; Djakovitch Laurent | Zendy; Gloaguen Bruno | Zendy; Thiel Werner | Zendy; Fillaut JeanLuc | Zendy; Delville MarieHélène | Zendy; Astruc Didier | Zendy; Boese Roland | Zendy

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Organometallic Molecular Trees as Multielectron and Multiproton Reservoirs: CpFe + ‐Induced Nonaallylation of Mesitylene and Phase‐Transfer Catalyzed Synthesis of a Redox‐Active Nonairon Complex

Author(s) -

Moulines Françoise,

Djakovitch Laurent,

Gloaguen Bruno,

Thiel Werner,

Fillaut JeanLuc,

Delville MarieHélène,

Astruc Didier,

Boese Roland

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199310751

Subject(s) - mesitylene , redox , catalysis , chemistry , phase (matter) , photochemistry , electron transfer , inorganic chemistry , organic chemistry

A reservoir of 9 electrons and 27 protons , complex 1 has 8±1 quasi‐equivalent redox centers. It is prepared from [CpFe(η 6 ‐mesitylene)] + by nonaallylation of the three methyl substituents, demetalation, conversion into the corresponding nonaol, and phasetransfer‐catalyzed reaction with [CpFe(FC 6 H 4 Me)].

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