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Structural Evidence of the Aromaticity of Borepins: A Comparison of 1‐Chloroborepin and Tricarbonyl(1‐chloroborepin)molybdenum
Author(s) -
Ashe Arthur J.,
Kampf Jeff W.,
Klein Wolfram,
Rousseau Roger
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199310651
Subject(s) - aromaticity , molybdenum , chemistry , planar , presumption , crystallography , symmetry (geometry) , computational chemistry , stereochemistry , molecule , inorganic chemistry , organic chemistry , mathematics , computer science , geometry , computer graphics (images) , political science , law
A planar structure with C 2v symmetry is a description of 1‐chloroborepin 1 , and is consistent with the presumption that 1 and probably also 1 H ‐borepin are aromatic compounds. The Mo(CO) 3 complex was prepared from 1 . Its structure was also determined, and it could be reduced to the stable complex 2 .