Structural Evidence of the Aromaticity of Borepins: A Comparison of 1‐Chloroborepin and Tricarbonyl(1‐chloroborepin)molybdenum | Zendy

Ashe Arthur J. | Zendy; Kampf Jeff W. | Zendy; Klein Wolfram | Zendy; Rousseau Roger | Zendy

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Structural Evidence of the Aromaticity of Borepins: A Comparison of 1‐Chloroborepin and Tricarbonyl(1‐chloroborepin)molybdenum

Author(s) -

Ashe Arthur J.,

Kampf Jeff W.,

Klein Wolfram,

Rousseau Roger

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199310651

Subject(s) - aromaticity , molybdenum , chemistry , planar , presumption , crystallography , symmetry (geometry) , computational chemistry , stereochemistry , molecule , inorganic chemistry , organic chemistry , mathematics , computer science , geometry , computer graphics (images) , political science , law

A planar structure with C 2v symmetry is a description of 1‐chloroborepin 1 , and is consistent with the presumption that 1 and probably also 1 H ‐borepin are aromatic compounds. The Mo(CO) 3 complex was prepared from 1 . Its structure was also determined, and it could be reduced to the stable complex 2 .

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