Tetrakis(tri‐ tert ‐butylsilyl)‐ tetrahedro ‐tetrasilane ( t Bu 3 Si) 4 Si 4 : The First Molecular Silicon Compound with a Si 4  Tetrahedron | Zendy

Wiberg Nils | Zendy; Finger Christian M. M. | Zendy; Polborn Kurt | Zendy

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Tetrakis(tri‐ tert ‐butylsilyl)‐ tetrahedro ‐tetrasilane ( t Bu 3 Si) 4 Si 4 : The First Molecular Silicon Compound with a Si 4 Tetrahedron

Author(s) -

Wiberg Nils,

Finger Christian M. M.,

Polborn Kurt

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199310541

Subject(s) - tetracyanoethylene , bromine , silicon , yield (engineering) , chemistry , derivative (finance) , orange (colour) , medicinal chemistry , materials science , organic chemistry , economics , financial economics , metallurgy , food science

Yellow‐orange tetrakis(supersilyl)‐ tetrahedro ‐ tetrasilane ( 1 ), the first derivative of tetrahedro ‐tetrasilane Si 4 H 4 , is stable to heat, light, water, and air, and is not reduced by sodium at temperatures below 70°C, but reacts with oxidants like tetracyanoethylene and bromine. Compound 1 was obtained in 57% yield from reaction (a).

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