1‐Chloro‐2,2‐bis(4‐chlorophenyl)‐1‐lithioethene · TMEDA · 2THF: Structure of a LiCl Carbenoid | Zendy

Boche Gernot | Zendy; Marsch Michael | Zendy; Müller Achim | Zendy; Harms Klaus | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

1‐Chloro‐2,2‐bis(4‐chlorophenyl)‐1‐lithioethene · TMEDA · 2THF: Structure of a LiCl Carbenoid

Author(s) -

Boche Gernot,

Marsch Michael,

Müller Achim,

Harms Klaus

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199310321

Subject(s) - carbenoid , substituent , chemistry , crystal structure , nucleophile , stereochemistry , medicinal chemistry , atom (system on chip) , trigonal crystal system , catalysis , crystallography , rhodium , organic chemistry , computer science , embedded system

The ClCl bond in the carbenoid 1 is about 12 pm longer than that in the compound containing a H atom in place of the Li substituent. This explains the facile reaction of carbenoids with the nucleophiles RLi. The X‐ray crystal structure of 1 is consistent with 13 C‐NMR data, as well as with the stereochemistry of reactions of carbenoids with RLi or the Fritsch–Buttenberg–Wiechell rearrangement of vinyl carbenoids.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research