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Cage Extension to Clusters with Co 2 /Co 3 MoAs 6 Polyhedron Frameworks
Author(s) -
Detzel Michaela,
Pfeiffer Karl,
Scherer Otto J.,
Wolmershäuser Gotthelf
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199309141
Subject(s) - polyhedron , cage , extension (predicate logic) , ideal (ethics) , combinatorics , heteroatom , crystallography , mathematics , chemistry , computer science , ring (chemistry) , programming language , philosophy , organic chemistry , epistemology
Good yields of the heteroatom clusters 1 and 2 were obtained by deliberate cage extension. The Co 3 MoAs 6 polyhedral framework of 2 corresponds to a distorted sphenocorona. The ideal polyhedral sphenocorona with 10 corners, 14 faces, and 22 edges is shown right. Cp* = η 5 ‐C 5 Me 5 .