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Control of the Linkage of Inorganic Fragments of VO Compounds: From Cluster Shells as Carcerands via Cluster Aggregates to Solid‐State Structures
Author(s) -
Müller Achim,
Rohlfing Ralf,
Krickemeyer Erich,
Bögge Hartmut
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199309091
Subject(s) - tetrahedron , cluster (spacecraft) , polyhedron , octahedron , template , crystallography , container (type theory) , solid state , linkage (software) , chemistry , materials science , nanotechnology , crystal structure , combinatorics , computer science , mathematics , composite material , biochemistry , gene , programming language
Anionic templates such as NO 3 −and SCN − as well as H 2 O can direct the linking of VO polyhedra (octahedra, tetrahedra, square pyramids). What forms are “container compounds” with the template either in the central cavity, as seen in 1 , or on the outside wall.