Control of the Linkage of Inorganic Fragments of VO Compounds: From Cluster Shells as Carcerands via Cluster Aggregates to Solid‐State Structures | Zendy

Müller Achim | Zendy; Rohlfing Ralf | Zendy; Krickemeyer Erich | Zendy; Bögge Hartmut | Zendy

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Control of the Linkage of Inorganic Fragments of VO Compounds: From Cluster Shells as Carcerands via Cluster Aggregates to Solid‐State Structures

Author(s) -

Müller Achim,

Rohlfing Ralf,

Krickemeyer Erich,

Bögge Hartmut

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199309091

Subject(s) - tetrahedron , cluster (spacecraft) , polyhedron , octahedron , template , crystallography , container (type theory) , solid state , linkage (software) , chemistry , materials science , nanotechnology , crystal structure , combinatorics , computer science , mathematics , composite material , biochemistry , gene , programming language

Anionic templates such as NO 3 −and SCN − as well as H 2 O can direct the linking of VO polyhedra (octahedra, tetrahedra, square pyramids). What forms are “container compounds” with the template either in the central cavity, as seen in 1 , or on the outside wall.

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