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CH Bond Addition to a VNR Bond: Hydrocarbon Activation by a Sterically Crowded Vanadium System
Author(s) -
de With Jan,
Horton Andrew D.
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199309031
Subject(s) - vanadium , chemistry , steric effects , benzene , hydrocarbon , thermal decomposition , bond cleavage , medicinal chemistry , decomposition , double bond , stereochemistry , photochemistry , inorganic chemistry , polymer chemistry , organic chemistry , catalysis
Alkanes, alkenes, and benzene are activated by intermediate 1 , which has a three‐coordinate vanadium center, by the addition of a CH bond to one of the VN bonds. The unstable complex 1 is generated from [RNV(NHR) 2 R′] on thermolysis. R = t Bu 3 Si.
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