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Self Assembly of a New Class of Tetranuclear Copper( I ) and Silver( I ) Complexes
Author(s) -
Ziessel Raymond,
Youinou MarieThérèse
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199308771
Subject(s) - rhombus , copper , chemistry , crystallography , ion , ligand (biochemistry) , tetrahedron , stereochemistry , receptor , organic chemistry , mathematics , biochemistry , geometry
Two bipyridine units in the macrocycle and two phenanthroline arms are the noteworthy features of the new ligand 1 , which reacts spontaneously with Cu I and Ag I ions to form tetranuclear, double‐stranded helicates. In the copper complex the Cu ions, which have distorted tetrahedral coordination, lie at the corners of a regular rhombus.
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