Transition‐Metal‐Substituted Volatile Alanes, Gallanes, and Indanes: Synthesis and Structure | Zendy

Fischer Roland A. | Zendy; Behm Joachim | Zendy; Priermeier Thomas | Zendy; Scherer Wolfgang | Zendy

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Transition‐Metal‐Substituted Volatile Alanes, Gallanes, and Indanes: Synthesis and Structure

Author(s) -

Fischer Roland A.,

Behm Joachim,

Priermeier Thomas,

Scherer Wolfgang

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199307461

Subject(s) - transition metal , metal , chemistry , decomposition , acceptor , group 2 organometallic chemistry , nothing , organic chemistry , stereochemistry , molecule , catalysis , physics , condensed matter physics , philosophy , epistemology

The instability and tendency to disproportionate of organometallic compounds of Group 13 metal‐d‐metal complexes were countered by adjusting the donor/acceptor properties of the metal centers. Now nothing prevents the use of this class of compounds in layering processes or the development of its chemistry. A large number of alanes, gallanes, and indanes related to 1 (M Fe, L Cp, n 2) that are volatile without decomposition were prepared.

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