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Transition‐Metal‐Substituted Volatile Alanes, Gallanes, and Indanes: Synthesis and Structure
Author(s) -
Fischer Roland A.,
Behm Joachim,
Priermeier Thomas,
Scherer Wolfgang
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199307461
Subject(s) - transition metal , metal , chemistry , decomposition , acceptor , group 2 organometallic chemistry , nothing , organic chemistry , stereochemistry , molecule , catalysis , physics , condensed matter physics , philosophy , epistemology
The instability and tendency to disproportionate of organometallic compounds of Group 13 metal‐d‐metal complexes were countered by adjusting the donor/acceptor properties of the metal centers. Now nothing prevents the use of this class of compounds in layering processes or the development of its chemistry. A large number of alanes, gallanes, and indanes related to 1 (M Fe, L Cp, n 2) that are volatile without decomposition were prepared.