The Synthesis and Ab Initio Structure Determination of Zn 4 O(BO 3 ) 2 , a Microporous, Zincoborate Constructed of “Fused” Subunits, of Three‐ and Five‐Membered Rings | Zendy

Harrison William T. A. | Zendy; Gier Thurman E. | Zendy; Stucky Galen D. | Zendy

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The Synthesis and Ab Initio Structure Determination of Zn 4 O(BO 3 ) 2 , a Microporous, Zincoborate Constructed of “Fused” Subunits, of Three‐ and Five‐Membered Rings

Author(s) -

Harrison William T. A.,

Gier Thurman E.,

Stucky Galen D.

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199307241

Subject(s) - microporous material , ab initio , molecular sieve , aluminosilicate , crystallography , tetrahedron , materials science , ab initio quantum chemistry methods , chemistry , molecule , adsorption , catalysis , organic chemistry , composite material

Vertex‐sharing tetrahedral ZnO 4 and triangular BO 3 subunits form a three‐dimensional network of intersecting channels in Zn 4 O(BO 3 ) 2 a new molecular sieve not belonging to the aluminosilicates. The ab initio structure determination was possible with X‐ray powder data; the picture on the right shows the view along [100].

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