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The Synthesis and Ab Initio Structure Determination of Zn 4 O(BO 3 ) 2 , a Microporous, Zincoborate Constructed of “Fused” Subunits, of Three‐ and Five‐Membered Rings
Author(s) -
Harrison William T. A.,
Gier Thurman E.,
Stucky Galen D.
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199307241
Subject(s) - microporous material , ab initio , molecular sieve , aluminosilicate , crystallography , tetrahedron , materials science , ab initio quantum chemistry methods , chemistry , molecule , adsorption , catalysis , organic chemistry , composite material
Vertex‐sharing tetrahedral ZnO 4 and triangular BO 3 subunits form a three‐dimensional network of intersecting channels in Zn 4 O(BO 3 ) 2 a new molecular sieve not belonging to the aluminosilicates. The ab initio structure determination was possible with X‐ray powder data; the picture on the right shows the view along [100].