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Reduction of a Tetraaryldigallane to Afford a Radical Anion with GaGa Multiple Bonding Character
Author(s) -
He Xiaoming,
Bartlett Ruth A.,
Olmstead Marilyn M.,
RuhlandtSenge Karin,
Sturgeon Bradley E.,
Power Philip P.
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199307171
Subject(s) - gallium , character (mathematics) , ion , chemistry , reduction (mathematics) , crystallography , organic chemistry , mathematics , geometry
The shortening of the GaGa bond in Trip 2 GaGaTrip 2 ( 1 , TripH 2,4,6‐ i Pr 3 C 6 H 3 ) by 0.17 Å to 2.343(2) Å on formation of the radical anion 1 ˙− is due, at least in part, to the formation of a one‐electron π bond between the gallium atoms.
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