The P4‐Phosphazene Base as Part of a New Metal‐Free Initiator System for the Anionic Polymerization of Methyl Methacrylate | Zendy

Pietzonka Thomas | Zendy; Seebach Dieter | Zendy

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The P4‐Phosphazene Base as Part of a New Metal‐Free Initiator System for the Anionic Polymerization of Methyl Methacrylate

Author(s) -

Pietzonka Thomas,

Seebach Dieter

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199307161

Subject(s) - phosphazene , polymer chemistry , living anionic polymerization , methyl methacrylate , polymerization , methacrylate , chemistry , anionic addition polymerization , base (topology) , organic chemistry , polymer , mathematical analysis , mathematics

Poly(methyl methacrylate)s with narrow polydispersities can be prepared by anionic polymerization of methyl methacrylate by using the ethyl acetate/P4 base initiator system (see below). Depending on the reaction conditions, molecular weights of M n > 40 kg mol −1 can be obtained.

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