Premium
Molecular Recognition of Hexaaqua Transition Metal( II ) Ions
Author(s) -
Auerbach Ulf,
Stockheim Claudia,
Weyhermüller Thomas,
Wieghardt Karl,
Nuber Bernhard
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199307141
Subject(s) - coordination sphere , chemistry , octahedron , crystallography , ion , acetone , metal ions in aqueous solution , transition metal , stereochemistry , crystal structure , biochemistry , catalysis , organic chemistry
Six OH…O contacts in the second coordination sphere are formed when the octahedral neutral complexes [M III L] ( 1 , M Cr, Fe; for L see the structural formula on the right) react in acetone with [M′ II (OH 2 ) 6 ] 2+ ions (M′ Mn, Co, Ni, Zn) to give the complexes [ 1 {M′ II (OH 2 ) 6 } 1 ] 2+ . In contrast, [Co III L] coordinates in the first coordination sphere to give the complexes [LCoM′ II CoL] 2+ .
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom