Formation and Complex Stabilization of a New Chainlike Phosphazene Anion by Co  II  ‐Assisted Oxidative Scrambling of [N(PPh 2 ) 2 ] − | Zendy

Ellermann Jochen | Zendy; Sutter Jörg | Zendy; Knoch Falk A. | Zendy; Moll Matthias | Zendy

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Formation and Complex Stabilization of a New Chainlike Phosphazene Anion by Co II ‐Assisted Oxidative Scrambling of [N(PPh 2 ) 2 ] −

Author(s) -

Ellermann Jochen,

Sutter Jörg,

Knoch Falk A.,

Moll Matthias

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199307001

Subject(s) - phosphazene , cobalt , chemistry , amide , ion , medicinal chemistry , lithium (medication) , polymer chemistry , oxidizing agent , derivative (finance) , scrambling , inorganic chemistry , organic chemistry , medicine , financial economics , economics , endocrinology , polymer , linguistics , philosophy

Cobalt( II ) chloride acts as an oxidizing agent toward lithium bis(diphenylphosphino)amide ! Surprisingly, in boiling toluene the two components (molar ratio 1:2) form a phosphazene anion with scrambling of the amide, which reacts further with cobalt( II ) to give the spirocyclic metallaphosphazene 1 .

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