Novel V III  Complexes with a Central [V 3 (μ 3 ‐S)‐(μ‐S 2 ) 3 ] +  or [V 2 (μ‐O)(μ‐SPh) 2 ] 2+  Unit | Zendy

Dean Norman S. | Zendy; Folting Kirsten | Zendy; Lobkovsky Emil | Zendy; Christou George | Zendy

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Novel V III Complexes with a Central [V 3 (μ 3 ‐S)‐(μ‐S 2 ) 3 ] + or [V 2 (μ‐O)(μ‐SPh) 2 ] 2+ Unit

Author(s) -

Dean Norman S.,

Folting Kirsten,

Lobkovsky Emil,

Christou George

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199305941

Subject(s) - crystallography , vanadium , ligand (biochemistry) , atom (system on chip) , chemistry , physics , atomic physics , inorganic chemistry , biochemistry , receptor , computer science , embedded system

Positioned in the middle of the V 3 triangle in complex 1 , whose edges are bridged asymmetrically by three S 2 2−ligands, is a μ 3 ‐sulfido ligand (the central unit of 1 is shown on the right). In addition each V atom is coordinated to a terminal bipyridyl ligand. This structure type is new for vanadium complexes.

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