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Novel V III Complexes with a Central [V 3 (μ 3 ‐S)‐(μ‐S 2 ) 3 ] + or [V 2 (μ‐O)(μ‐SPh) 2 ] 2+ Unit
Author(s) -
Dean Norman S.,
Folting Kirsten,
Lobkovsky Emil,
Christou George
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199305941
Subject(s) - crystallography , vanadium , ligand (biochemistry) , atom (system on chip) , chemistry , physics , atomic physics , inorganic chemistry , biochemistry , receptor , computer science , embedded system
Positioned in the middle of the V 3 triangle in complex 1 , whose edges are bridged asymmetrically by three S 2 2−ligands, is a μ 3 ‐sulfido ligand (the central unit of 1 is shown on the right). In addition each V atom is coordinated to a terminal bipyridyl ligand. This structure type is new for vanadium complexes.