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[Cr(CO) 5 PCl 3 ]—A P 1 Building Block for the Formation of Complexes with cyclo ‐P x Ligands ( x = 3, 5)
Author(s) -
Scheer Manfred,
Friedrich Gabriele,
Schuster Kay
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199305931
Subject(s) - block (permutation group theory) , chemistry , crystallography , transition metal , stereochemistry , bond length , combinatorics , crystal structure , mathematics , organic chemistry , catalysis
Multiple PP bond formation in the coordination sphere of transition metals occurs in reactions of [Cr(CO) 5 PCl 3 ] with carbonylcyclopentadienylmolybdenates and ‐ferrates. Complexes with cyclo ‐P 3 and cyclo ‐P 5 ligands (like 1 ), respectively, result.
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