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Novel Triselenidotantalum Halfsandwich Complexes
Author(s) -
Tatsumi Kazuyuki,
Kawaguchi Hiroyuki,
Tani Kazuhide
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199305911
Subject(s) - ideal (ethics) , cube (algebra) , atom (system on chip) , bridge (graph theory) , crystallography , chemistry , stereochemistry , materials science , mathematics , combinatorics , computer science , biology , philosophy , parallel computing , anatomy , epistemology
An almost ideal cube‐shaped TaSe 3 Li 3 Cl framework is found in complex 1 , the first organometallic complex with three monoselenido ligands. The three Li atoms each bridge two Se ligands and together are capped by the Cl atom.