[MnM(egta)] · 8H 2 O (M = Mn, Cd): A Novel Type of Two‐Dimensional Magnetic Lattice | Zendy

BorrásAlmenar Juan J. | Zendy; Coronado Eugenio | Zendy; GómezGarcia Carlos J. | Zendy; Ouahab Lahcène | Zendy

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[MnM(egta)] · 8H 2 O (M = Mn, Cd): A Novel Type of Two‐Dimensional Magnetic Lattice

Author(s) -

BorrásAlmenar Juan J.,

Coronado Eugenio,

GómezGarcia Carlos J.,

Ouahab Lahcène

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199305611

Subject(s) - antiferromagnetism , egta , lattice (music) , ion , crystallography , chemistry , condensed matter physics , physics , materials science , nuclear magnetic resonance , stereochemistry , calcium , organic chemistry , acoustics

Extended layered networks in which [M(egta)] 2− is eight‐coordinate and Mn 2+ six‐coordinate are present in the title compounds. In the case of the Mn 2 compound this leads to the novel two‐dimensional lattice sketched on the right; short range antiferromagnetic exchange interactions between the Mn II ions were found. H 4 egta = ethylenedioxybis(ethylenenitrilo)tetraacetic acid; the circles represent the magnetically nonequivalent Mn II ions.

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