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Premium A Simple One‐Step Synthesis of Symmetrical Thiocrown Ethers and the Molecular Structure of an Unusual Sandwich‐like Tetrametallic Silver Thiocrown Ether Complex
Author(s)
Edema Jilles J. H.,
Stock H. Thijs,
Buter Jan,
Kellogg Richard M.,
Smeets Wilberth J. J.,
Spek Anthony L.,
van Bolhuis Fre
Publication year1993
Publication title
angewandte chemie international edition in english
Resource typeJournals
PublisherHüthig & Wepf Verlag
Also in the presence of functional groups , the 2 + 2 cyclization of 1 and 2 to give thiocrown ethers 3 is achieved in good yields, if B(O i Pr) 3 /Al(O i Pr) 3 ) is present. Furthermore a sandwich‐like cationic complex [Ag 4 ‐( 3b ) 2 ] 4+ was prepared with 3b . This complex is also stable in solution.
Subject(s)cationic polymerization , chemistry , epistemology , ether , molecule , organic chemistry , philosophy , polymer chemistry , simple (philosophy)
Language(s)English
SCImago Journal Rank5.831
H-Index550
eISSN1521-3773
pISSN0570-0833
DOI10.1002/anie.199304361

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