Fixation and Reduction of Dinitrogen by Vanadium( II ) and Vanadium( III ): Synthesis and Structure of Dinitrogenmesitylvanadium Complexes | Zendy

Ferguson Richard | Zendy; Solari Euro | Zendy; Floriani Carlo | Zendy; ChiesiVilla Angiola | Zendy; Rizzoli Corrado | Zendy

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Fixation and Reduction of Dinitrogen by Vanadium( II ) and Vanadium( III ): Synthesis and Structure of Dinitrogenmesitylvanadium Complexes

Author(s) -

Ferguson Richard,

Solari Euro,

Floriani Carlo,

ChiesiVilla Angiola,

Rizzoli Corrado

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199303961

Subject(s) - vanadium , protonation , chemistry , ion , crystallography , medicinal chemistry , sodium , inorganic chemistry , stereochemistry , organic chemistry

Two short VN bonds and a long NN bond , as well as a sodium atom that is situated in the cavity created by the VNNV unit and two mesityl (mes) ligands are the intriguing characteristics of the anion of complex 1 . It is formed by the reduction of [V(mes) 3 (thf)] with Na under N 2 and on protonation yields NH 3 and N 2 H 4 . Two mes ligands at both V and V′ are omitted from the picture shown on the right.

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