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Synthesis, Properties, and Structure of —A New Type of Pt II Metallacyclopentane Complexes
Author(s) -
Fröhlich HansOtto,
Wyrwa Ralf,
Görls Helmar
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199303871
Subject(s) - tetramethylethylenediamine , platinum , butane , chemistry , cyclooctadiene , crystallography , stereochemistry , medicinal chemistry , catalysis , organic chemistry
The highly symmetrical compound 1 decomposes only at 249 °C despite the β‐hydrogen atoms of the two butane‐1,4‐diyl groups at the platinum( II ) center. Compound 1 is formed from the reaction of [(1,5‐cod)PtCl 2 ] (cod = 1,5‐cyclooctadiene) with 1,4‐Li 2 C 4 H 8 and N, N, N′, N′ ‐tetramethylethylenediamine.