1‐Hetero‐3,4‐diborolanes and Two New Routes to 1,2‐Diboretanes ** | Zendy

Littger Ralf | Zendy; Nöth Heinrich | Zendy; Thomann Martina | Zendy; Wagner Matthias | Zendy

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1‐Hetero‐3,4‐diborolanes and Two New Routes to 1,2‐Diboretanes **

Author(s) -

Littger Ralf,

Nöth Heinrich,

Thomann Martina,

Wagner Matthias

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199302951

Subject(s) - oxidative coupling of methane , derivative (finance) , sunlight , chemistry , coupling (piping) , medicinal chemistry , oxidative phosphorylation , computational chemistry , photochemistry , physics , organic chemistry , materials science , catalysis , quantum mechanics , business , finance , metallurgy , biochemistry

In sunlight, 1‐plumba‐3,4‐diborolane 1 reacts to form the 1,2‐diboretan derivative 2 . This rearranges on warming to the thermodynamically more stable 1,3 isomer 3 . Compound 2 is also accessible from the corresponding diboratabutadiene dianion by oxidative coupling.

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