Premium
[Fe 2 Cl 6 ] 2− : A Discrete Form of Ferrous Chloride
Author(s) -
Dunbar Kim R.,
Quillevéré Anne
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199302931
Subject(s) - ferrous , chloride , chemistry , materials science , metallurgy
Two edge‐sharing FeCl 4 tetrahedra with two terminal and two bridging Cl ligands per metal center describes the title anion 1 (structure shown) isolated as a phosphonium salt. The Fe…Fe distance in this unprecedented dinuclear iron( II ) compound is 3.350(4) Å.