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A Hemerythrin Model Complex with Catalase Activity
Author(s) -
Mauerer Bert,
Crane Jonathan,
Schuler Jürgen,
Wieghardt Karl,
Nuber Bernhard
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199302891
Subject(s) - disproportionation , chemistry , catalysis , catalytic cycle , ligand (biochemistry) , catalase , active site , stereochemistry , enzyme , biochemistry , receptor
The catalytic disproportionation of H 2 O 2 to O 2 and H 2 O is achieved with the asymmetric hemerythrin model complex 1 , which has a reactive coordination site. The catalytic cycle proceeds via the oxyhemerythrin form with a coordinated hydrogenperoxo ligand. L 1,4,7‐trimethyl‐1,4,7‐triazacyclononane, bpy 2,2′‐bipyridine.
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