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Ca 2 PN 3 : A New Phosphorus( V ) Nitride with One‐Dimensional Infinite Chains of Corner‐Sharing PN 4 Tetrahedra
Author(s) -
Schnick Wolfgang,
SchultzCoulon Verena
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199302801
Subject(s) - tetrahedron , phosphorus , nitride , chemistry , crystallography , materials science , organic chemistry , layer (electronics)
Low‐dimensional coupling analogous to that in chainlike silicates can also occur in phosphorus( V ) nitrides. Infinite chains of corner‐sharing PN 4 tetrahedra (schematically shown below) are present in the complex anion Ca 2 PN 3 .