Iodine Azide | Zendy

Buzek Peter | Zendy; Klapötke Thomas M. | Zendy; von Ragué Schleyer Paul | Zendy; TornieporthOetting Inis C. | Zendy; White Peter S. | Zendy

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Iodine Azide

Author(s) -

Buzek Peter,

Klapötke Thomas M.,

von Ragué Schleyer Paul,

TornieporthOetting Inis C.,

White Peter S.

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199302751

Subject(s) - azide , iodine , sublimation (psychology) , chemistry , solid state , materials science , crystallography , organic chemistry , psychology , psychotherapist

Very pure and crystalline, iodine azide IN 3 ( 1 ) can be obtained by reaction of silver azide and iodine in CFCl 3 and subsequent sublimation. According to the results of the X‐ray structure analysis in the solid state IN 3 consists of layers of chains, which contain twofold coordinated iodine atoms. The structural parameters of the IN 3 unit are in good agreement with the results of an ab initio calculation for IN 3 .

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