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Iodine Azide
Author(s) -
Buzek Peter,
Klapötke Thomas M.,
von Ragué Schleyer Paul,
TornieporthOetting Inis C.,
White Peter S.
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199302751
Subject(s) - azide , iodine , sublimation (psychology) , chemistry , solid state , materials science , crystallography , organic chemistry , psychology , psychotherapist
Very pure and crystalline, iodine azide IN 3 ( 1 ) can be obtained by reaction of silver azide and iodine in CFCl 3 and subsequent sublimation. According to the results of the X‐ray structure analysis in the solid state IN 3 consists of layers of chains, which contain twofold coordinated iodine atoms. The structural parameters of the IN 3 unit are in good agreement with the results of an ab initio calculation for IN 3 .