Selective Photolabeling near the Middle of Bilayers with a Photosensitive Transmembrane Probe | Zendy

Yamamoto Masakuni | Zendy; Warnock William A. | Zendy; Milon Alain | Zendy; Nakatani Yoichi | Zendy; Ourisson Guy | Zendy

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Selective Photolabeling near the Middle of Bilayers with a Photosensitive Transmembrane Probe

Author(s) -

Yamamoto Masakuni,

Warnock William A.,

Milon Alain,

Nakatani Yoichi,

Ourisson Guy

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199302591

Subject(s) - vesicle , phospholipid , chemistry , membrane , transmembrane protein , selectivity , biophysics , lipid bilayer , photochemistry , biochemistry , biology , receptor , catalysis

The efficient study of the inside of a membrane should no longer be a problem, thanks to the investigations described here. In vesicles from phospholipids, incorporated 1 (X H,D) reacts upon irradiation with a selectivity up to 90% at positions ω −1 and ω −2 of the phospholipid chains, when, at the same time, cholesterol is a constituent of the membrane in normal bioconcentrations.

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