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New Phosphido‐Bridging Copper Clusters
Author(s) -
Eichhöfer Andreas,
Fenske Dieter,
Holstein Werner
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199302421
Subject(s) - copper , bridging (networking) , chemistry , chloride , inorganic chemistry , organic chemistry , computer science , computer network
The way to polymeric copper phosphides is probably marked by multinuclear Cu clusters accessible from copper chloride and functionalized phosphanes. One of the multitude of new compounds with unusual structures prepared from these starting materials is [Cu 12 (PPh) 6 (PPh 3 ) 6 ], whose central CuP framework is shown here.