A Self‐Assembling, Hydrogen‐Bonded Helix | Zendy

Geib Steven J. | Zendy; Vicent Cristina | Zendy; Fan Erkang | Zendy; Hamilton Andrew D. | Zendy

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A Self‐Assembling, Hydrogen‐Bonded Helix

Author(s) -

Geib Steven J.,

Vicent Cristina,

Fan Erkang,

Hamilton Andrew D.

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199301191

Subject(s) - ribbon , hydrogen bond , planar , molecule , derivative (finance) , crystallography , materials science , helix (gastropod) , structural motif , chemistry , organic chemistry , computer science , composite material , biochemistry , computer graphics (images) , snail , ecology , financial economics , economics , biology

The same structural motif but different shapes in space characterize the polymeric 1:1 complexes constructed from the isophthalate derivative 1 and the two dicarboxylic acids 2 . Although both aggregates are stabilized by two pairs of hydrogen bonds between neighboring molecules, the complex formed with the longer dicarboxylic acid has a helical structure, the shorter, a planar ribbon structure.

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