Axial Ligation of Diazacyclooctanenickel and ‐Zinc Complexes | Zendy

Goodman Dawn C. | Zendy; Tuntulani Thawatchai | Zendy; Farmer Patrick J. | Zendy; Darensbourg Marcetta Y. | Zendy; Reibenspies Joseph H. | Zendy

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Axial Ligation of Diazacyclooctanenickel and ‐Zinc Complexes

Author(s) -

Goodman Dawn C.,

Tuntulani Thawatchai,

Farmer Patrick J.,

Darensbourg Marcetta Y.,

Reibenspies Joseph H.

Publication year - 1993

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199301161

Subject(s) - hexacoordinate , crystallography , zinc , molecule , nickel , center (category theory) , ligand (biochemistry) , metal , chemistry , paramagnetism , atom (system on chip) , hydrogen bond , group (periodic table) , physics , organic chemistry , silicon , computer science , biochemistry , receptor , embedded system , quantum mechanics

Thanks to the unusual folding of the diazacyclooctane ligand, which normally blocks an axial position of the metal center, the paramagnetic, blue nickel complex 1 containing a hexacoordinate central Ni atom could be synthesized. In the crystal the O atom of the carboxyl group not coordinated to the Ni center participates in hydrogen bonding with water molecules to form a three‐dimensional network.

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