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Two Modifications of a Cyclopentadienylthallium( I ) Complex Linking the Chemistry of the Cp and Arene Complexes of Main Group Elements
Author(s) -
Frank Walter,
Kuhn Dietmar,
MüllerBecker Stefan,
Razavi Abbas
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199300901
Subject(s) - thallium , chemistry , monomer , group (periodic table) , molecule , metal , crystallography , complex formation , coordination complex , main group element , stereochemistry , polymer , inorganic chemistry , transition metal , organic chemistry , catalysis
The simultaneous coordination of a main group metal to both Cp and arene ligands was proven by crystallographic studies of two modifications of the thallium complex of 1 . The thallium atoms are surrounded by three aromatic systems forming chains and layers of coordination polymers. In solution the monomeric molecules of the complex display dynamic behavior.