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New Half‐Sandwich Polysulfidorhenium Complexes
Author(s) -
Herberhold Max,
Jin GuoXin,
Milius Wolfgang
Publication year - 1993
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199300851
Subject(s) - chemistry
A ReRe bond is present in the almost C 2 symmetrical complex 1 containing a planar Re 2 S 2 unit. It forms from the desulfurization of 2 with PPh 3 . A notable structural element of the green complex 2 is the ReS 3 chelate ring, in which the Re‐S distances are significantly shorter than those in the S 4 2−chelate complex 1 .