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High‐Yield Synthesis of Lipid Systems with Giant Rings
Author(s) -
Menger Fredric M.,
Brocchini Stephen,
Chen Xiangyang
Publication year - 1992
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199214921
Subject(s) - yield (engineering) , aromaticity , chemistry , materials science , organic chemistry , molecule , composite material
A high‐temperature Glaser coupling reaction is the key to the efficient synthesis of lipids with “giant rings” as exemplified by reaction (a) (77% yield). Macrocyclic compounds are usually considered to have rings with twelve to twenty members; the term “giant rings” refers to compounds with even larger rings.
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