Cationic Metallocene Polymerization Catalysts. Synthesis and Properities of the First Base‐Free Zirconocene Hydride | Zendy

Yang Xinmim | Zendy; Stern Charlotte L. | Zendy; Marks Tobin J. | Zendy

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Cationic Metallocene Polymerization Catalysts. Synthesis and Properities of the First Base‐Free Zirconocene Hydride

Author(s) -

Yang Xinmim,

Stern Charlotte L.,

Marks Tobin J.

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199213751

Subject(s) - cationic polymerization , metallocene , hydride , hydrogenolysis , polymerization , chemistry , polymer chemistry , catalysis , natta , olefin polymerization , organic chemistry , polymer , hydrogen

High electrophilicity and polymerization activity as well as ion‐pairing effects not based on the bridging hydrogen atoms are the most notable characteristics of the cation in 2 , a model compound for Ziegler‐Natta catalysts. This hydrido complex is accessible by hydrogenolysis of 1 or by hydride abstraction from 3 .

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