[V(SNC 9 H 6 ) 3 ] and [V(SNH 2 C 6 H 4 ) 2 (SNHC 6 H 4 )] − , Homoleptic Vanadium( III ) Complexes with Sulfur–Nitrogen Donor Ligands, and [V(SNC 5 H 4 ) 3 ] − , the First Thiolatovanadium( II ) Complex | Zendy

Henkel Gerald | Zendy; Krebs Bernt | Zendy; Schmidt Wilfried | Zendy

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[V(SNC 9 H 6 ) 3 ] and [V(SNH 2 C 6 H 4 ) 2 (SNHC 6 H 4 )] − , Homoleptic Vanadium( III ) Complexes with Sulfur–Nitrogen Donor Ligands, and [V(SNC 5 H 4 ) 3 ] − , the First Thiolatovanadium( II ) Complex

Author(s) -

Henkel Gerald,

Krebs Bernt,

Schmidt Wilfried

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199213661

Subject(s) - vanadium , octahedron , chemistry , crystallography , atom (system on chip) , nitrogen atom , sulfur , octahedral molecular geometry , inorganic chemistry , crystal structure , ring (chemistry) , organic chemistry , computer science , embedded system

The sulfur and nitrogen atoms of the pyridinethiolato ligands coordinate to the central atom in the vanadium( II ) complex [V(SNC 5 H 4 )0 3 ] − (1) to form a distorted octahedral geometry. In each set of neighboring ligands one S atom and one N atom are trans to each other; the chelate rings are planar. Such complexes with bifunctional ligands are important as models for vanadium centers in biomolecules.

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