“[Cp * CoCoCp * ]” is a Hydride | Zendy

Kersten Jörg L. | Zendy; Rheingold Arnold L. | Zendy; Theopold Klaus H. | Zendy; Casey Charles P. | Zendy; Widenhoefer Ross A. | Zendy; Hop Cornelis E. C. A. | Zendy

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“[Cp * CoCoCp * ]” is a Hydride

Author(s) -

Kersten Jörg L.,

Rheingold Arnold L.,

Theopold Klaus H.,

Casey Charles P.,

Widenhoefer Ross A.,

Hop Cornelis E. C. A.

Publication year - 1992

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199213411

Subject(s) - cobalt , hydride , protonation , chemistry , carbonylation , paramagnetism , crystallography , medicinal chemistry , inorganic chemistry , catalysis , physics , carbon monoxide , organic chemistry , metal , ion , condensed matter physics

The supposed synthesis of the cobalt complex [Cp * CoCoCp * ] was in the spotlight at the end of last year ( Angew. Chem. Int. Ed. Engl. 1991, 30 , 1124). But the compound described at that time is actually the mixed‐valent cobalt hydride 2 . The reaction of the dinuclear complex 1 with LiAlH 4 yields two paramagnetic cobalt complexes ( 2 and 3 ), which have been fully characterized by X‐ray crystallography and spectroscopic methods, as well as by protonation and carbonylation. See also the Corrigendum on p. 1392.

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