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Azidoiodoiodine(1+) Hexafluoroantimonate: The First Binary Nitrogen–Iodine Cation
Author(s) -
TornieporthOetting Inis C.,
Buzek Peter,
Schleyer Paul von Ragué,
Klapötke Thomas M.
Publication year - 1992
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199213381
Subject(s) - raman spectroscopy , chemistry , ab initio , explosive material , binary number , iodine , nitrogen , ab initio quantum chemistry methods , inorganic chemistry , computational chemistry , molecule , organic chemistry , physics , optics , arithmetic , mathematics
A nonplanar, chainlike structure for the cation I 2 N 3 +is suggested by the findings of Raman spectroscopy and the results of ab initio calculations (depicted here). This unprecedented binary I‐N cation can be prepared by the reaction of IN 3 with I 2 /SbF 5 or of AgN 3 with I 3 SbF 6 . (Caution: explosive!)
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