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Hydride Transfer by Hydrido Transition‐Metal Complexes. Ionic Hydrogenation of Aldehydes and Ketones, and Structural Characterization of an Alcohol Complex
Author(s) -
Song JeongSup,
Szalda David J.,
Bullock R. Morris,
Lawrie Christophe J. C.,
Rodkin Mikhail A.,
Norton Jack R.
Publication year - 1992
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199212331
Subject(s) - hydride , alcohol , chemistry , protonation , transfer hydrogenation , ligand (biochemistry) , ionic bonding , crystal structure , transition metal , metal , molecule , organic chemistry , medicinal chemistry , inorganic chemistry , catalysis , ion , biochemistry , receptor , ruthenium
The rate‐determining step in the hydrogenation of aldehydes or ketones by hydrido complexes and acids appears to be the hydride transfer from the complex to the protonated carbonyl compound. The resulting alcohol is initially bound as ligand, as confirmed by an X‐ray crystal structure analysis of the alcohol complex 1 .